| 1 | –Maria Friedman | How Many Tears?Lyrics By – Alain Boublil, Stephen Clark Music By – Claude-Michel Schönberg |
| 2 | –Colm Wilkinson | The Music Of The NightLyrics By – Charles Hart, Richard StilgoeMusic By – Andrew Lloyd Webber |
| 3 | –Stephen Sondheim | Introduction |
| 4 | –Lea Salonga | On My OwnLyrics By – Alain Boublil, Herbert KretzmerMusic By – Claude-Michel Schönberg |
| 5 | –Michael Ball | Losing My MindLyrics By – Stephen SondheimMusic By – Stephen Sondheim |
| 6 | –Joanna Riding | You'll Never Walk AloneLyrics By – Oscar Hammerstein IIMusic By – Richard Rodgers |
| 7 | –Maria Friedman, Julie McKenzie & Bernadette Peters | Broadway BabyLyrics By – Stephen SondheimMusic By – Stephen Sondheim |
| 8 | –Jonathan Pryce | American DreamLyrics By – Alain Boublil, Richard Maltby Jr.Music By – Claude-Michel Schönberg |
| 9 | –Kevyn Beckett, Trent Kendall, Monroe Kent III, Jason Pennycooke, Clarke Peters & Richard D. Sharpe | Five Guys Named MoeLyrics By – Jerry Bresler, Larry Wynn, Louis JordanMusic By – Louis Jordan |
| 10 | –Julie Andrews | Introduction |
| 11 | –Lisa Vroman & Colm Wilkinson | The Phantom Of The OperaLyrics By – Charles Hart, Richard StilgoeMusic By – Andrew Lloyd Webber |
| 12 | –The City Of London Philharmonic | We Said We Wouldn't Look BackMusic By – Julian Slade |
| 13 | –The City Of London Philharmonic | At The End Of The DayLyrics By – Alain Boublil, Herbert KretzmerMusic By – Claude-Michel Schönberg |
| 14 | –Elaine Paige | MemoryLyrics By – T. S. Eliot, Trevor NunnMusic By – Andrew Lloyd Webber |
| 15 | –Jonathan Pryce & Liz Robertson | I've Grown Accustomed To Her FaceLyrics By – Alan Jay LernerMusic By – Frederick Loewe |
| 16 | –David Campbell & Lea Salonga | Last Night Of The WorldLyrics By – Alain Boublil, Richard Maltby Jr.Music By – Claude-Michel Schönberg |
| 17 | –Ellen Greene & Teddy Kempner | Suddenly SeymourLyrics By – Howard AshmanMusic By – Alan Menken |
| 18 | –Jimmy Logan & Scottish Power Pipe Band | I Love A LassieLyrics By – Harry LauderMusic By – Harry Lauder |
| 19 | –John Barrowman | One Two ThreeLyrics By – John DempseyMusic By – Dana P. Rowe |
| 20 | –Hal Fowler | Do You Hear The People Sing?Lyrics By – Alain Boublil, Herbert KretzmerMusic By – Claude-Michel Schönberg |
| 21 | –Stephen Sondheim & Andrew Lloyd Webber | Duelling PianosLyrics By – Stephen SondheimMusic By – Andrew Lloyd Webber, Stephen Sondheim |
| 22 | –Philip Quast | StarsLyrics By – Alain Boublil, Herbert KretzmerMusic By – Claude-Michel Schönberg |
| 23 | –Ellen Greene | Somewhere That's GreenLyrics By – Howard AshmanMusic By – Alan Menken |
| 24 | –Maria Friedman, Ruthie Henshall, Millicent Martin & Lea Salonga | You Could Drive A Person CrazyLyrics By – Stephen SondheimMusic By – Stephen Sondheim |
| 25 | –Jonathan Pryce, Liz Robertson & Donald Sinden | The Rain In SpainLyrics By – Alan Jay LernerMusic By – Frederick Loewe |
| 26 | –Marian Montgomery & Laurie Holloway | I Get A Kick Out Of YouLyrics By – Cole PorterMusic By – Cole Porter |
| 27 | –David Kernan, Millicent Martin & Julia McKenzie | Side By SideLyrics By – Stephen SondheimMusic By – Stephen Sondheim |
| 28 | –Wendy Mae Brown, Dawn Hope & Femi Taylor | Little Shop Of HorrorsLyrics By – Howard AshmanMusic By – Alan Menken |
| 29 | –Bernadette Peters | Being AliveLyrics By – Stephen SondheimMusic By – Stephen Sondheim |
| 30 | –Jasna Ivir | Nicer In NiceLyrics By – Sandy Wilson Music By – Sandy Wilson |
| 31 | –Peter Bayliss | Get Me To The Church On TimeLyrics By – Alan Jay LernerMusic By – Frederick Loewe |
| 32 | –The City Of London Philharmonic | Quit Professor HigginsLyrics By – Alan Jay LernerMusic By – Frederick Loewe |
| 33 | –David Campbell & Lea Salonga | The Heat Is On In SaigonLyrics By – Alain Boublil, Richard Maltby Jr.Music By – Claude-Michel Schönberg |
| 34 | –Ruthie Henshall, Julia McKenzie & Bernadette Peters | You've Gotta Have A GimmickLyrics By – Stephen SondheimMusic By – Jule Styne |
| 35 | –Colm Wilkinson | Bring Him HomeLyrics By – Alain Boublil, Herbert KretzmerMusic By – Claude-Michel Schönberg |
| 36 | –The City Of London Philharmonic | This Is The HourLyrics By – Alain Boublil, Richard Maltby Jr.Music By – Claude-Michel Schönberg |
| 37 | –Tom Lehrer | Poisoning Pigeons In The ParkLyrics By – Tom LehrerMusic By – Tom Lehrer |
| 38 | –The City Of London Philharmonic | Day By DayLyrics By – Stephen SchwartzMusic By – Stephen Schwartz |
| 39 | –Hal Fowler, Joanna Riding, Dana Stackpole & Barbara King | Porch SceneLyrics By – Oscar Hammerstein IIMusic By – Richard Rodgers |
| 40 | –Sonia Swaby | As Long As He Needs MeLyrics By – Lionel BartMusic By – Lionel Bart |
| 41 | –The City Of London Philharmonic | The WeddingLyrics By – Alain Boublil, Richard Maltby Jr.Music By – Claude-Michel Schönberg |
| 42 | –Julian Lloyd Webber | VariationsMusic By – Andrew Lloyd Webber |
| 43 | –The City Of London Philharmonic | Cats OvertureMusic By – Andrew Lloyd Webber |
| 44 | –Cameron Mackintosh | We Said We Wouldn't Look BackLyrics By – Dorothy ReynoldsMusic By – Julian Slade |
| 45 | –Ned Sherrin | Introduction |
| 46 | –David Campbell | I'm Martin GuerreLyrics By – Alain Boublil, Stephen Clark Music By – Claude-Michel Schönberg |
| 47 | –Judi Dench | Send In The ClownsLyrics By – Stephen SondheimMusic By – Stephen Sondheim |
| 48 | –Russ Abbot | Pick A PocketLyrics By – Lionel BartMusic By – Lionel Bart |
| 49 | –Liz Robertson | Wouldn't It Be Loverly?Lyrics By – Alan Jay LernerMusic By – Frederick Loewe |
| 50 | –Vadim Bondar & Dana Stackpole | Carousel Waltz/BalletLyrics By – Oscar Hammerstein IIMusic By – Richard Rodgers |
| 51 | –Brian Blessed & Paul Nicholas | Jellicle SongsLyrics By – T. S. Eliot, Trevor NunnMusic By – Andrew Lloyd Webber |
| 52 | –Kevyn Beckett, Trent Kendall, Monroe Kent III, Jason Pennycooke, Clarke Peters & Richard D. Sharpe | Is You Is Or Is You Ain't My BabyLyrics By – Jerry Bresler, Larry Wynn, Louis JordanMusic By – Louis Jordan |
| 53 | –Hugh Jackman | Oh, What A Beautiful Mornin'Lyrics By – Oscar Hammerstein IIMusic By – Richard Rodgers |
| 54 | –Colm Wilkinson, Michael Ball, Hal Fowler, Ruthie Henshall, Tammi Jacobs, Teddy Kempner, Philip Quast, Lea Salonga & Marie Zamora | One Day MoreLyrics By – Alain Boublil, Herbert KretzmerMusic By – Claude-Michel Schönberg |
| 55 | –Bernadette Peters | Unexpected SongLyrics By – Don Black, Richard Maltby Jr.Music By – Andrew Lloyd Webber |
| 56 | –The City Of London Philharmonic | Food Glorious FoodLyrics By – Lionel BartMusic By – Lionel Bart |