| 1 | –Marvin Gaye | How Sweet It Is (To Be Loved By You)Written-By – Edward Holland, Jr.Written-By, Producer – Brian Holland, Lamont Dozier | 2:58 |
| 2 | –The Miracles | The Tracks Of My TearsProducer – Smokey RobinsonWritten-By – Marv Tarplin, William "Smokey" Robinson, Warren Moore | 2:54 |
| 3 | –The Temptations | My GirlProducer – Ronnie White, Smokey RobinsonWritten-By – Ronald White, William "Smokey" Robinson | 2:42 |
| 4 | –The Temptations | Ball Of Confusion (That's What The World Is Today)Written-By – Barrett StrongWritten-By, Producer – Norman Whitfield | 4:04 |
| 5 | –Gladys Knight & The Pips | I Heard It Through The GrapevineWritten-By – Barrett StrongWritten-By, Producer – Norman Whitfield | 2:45 |
| 6 | –The Supremes | Stop! In The Name Of LoveWritten-By – Edward Holland, Jr.Written-By, Producer – Brian Holland, Lamont Dozier | 2:52 |
| 7 | –Little Stevie Wonder | Fingertips Pt. 2Producer – Berry GordyWritten-By – Henry CosbyWritten-By, Arranged By, Conductor – Clarence Paul | 3:21 |
| 8 | –The Marvelettes | Please Mr. PostmanProducer – BrianbertWritten-By – Brian Holland, Freddie Gorman, Georgia Dobbins, Robert Bateman, William Garrett | 2:28 |
| 9 | –The Miracles | Going To A Go-GoProducer – Smokey RobinsonWritten-By – Marv Tarplin, Robert Rogers, William "Smokey" RobinsonWritten-By, Producer – Warren Moore | 2:45 |
| 10 | –The Temptations | I Can't Get Next To YouWritten-By – Barrett StrongWritten-By, Producer – Norman Whitfield | 2:51 |
| 11 | –Smokey Robinson & The Miracles | The Tears Of A ClownProducer – Smokey RobinsonWritten-By – William "Smokey" Robinson, Stevie WonderWritten-By, Producer – Henry Cosby | 2:59 |
| 12 | –Four Tops | I Can't Help Myself (Sugar Pie, Honey Bunch)Written-By – Edward Holland, Jr.Written-By, Producer – Brian Holland, Lamont Dozier | 2:43 |
| 13 | –Mary Wells | You Beat Me To The PunchProducer – Smokey RobinsonWritten-By – Ronald White, William "Smokey" Robinson | 2:43 |
| 14 | –Stevie Wonder | UpTight (Everything's Alright)Producer – William "Mickey" StevensonWritten-By – Stevie Wonder, Sylvia MoyWritten-By, Producer – Henry Cosby | 2:52 |
| 15 | –Junior Walker & The All Stars | ShotgunProducer – Berry Gordy, Lawrence HornWritten-By – Autry DeWalt | 3:03 |
| 16 | –Barrett Strong | Money (That's What I Want)Written-By – Janie BradfordWritten-By, Producer – Berry Gordy | 2:34 |
| 17 | –Edwin Starr | WarWritten-By – Barrett StrongWritten-By, Producer – Norman Whitfield | 3:19 |
| 18 | –Marvin Gaye | I Heard It Through The GrapevineWritten-By – Barrett StrongWritten-By, Producer – Norman Whitfield | 3:13 |
| 19 | –The Supremes | Up The Ladder To The RoofArranged By – David Van DePitteWritten-By – Vincent DiMircoWritten-By, Producer – Frank Wilson | 3:11 |
| 20 | –Stevie Wonder | Signed, Sealed, Delivered I'm YoursArranged By – Paul RiserWritten-By – Lee Garrett, Lula Mae Hardaway, Syreeta WrightWritten-By, Producer – Stevie Wonder | 2:38 |
| 21 | –The Contours | Do You Love MeWritten-By, Producer – Berry Gordy | 2:52 |
| 22 | –The Spinners | It's A ShameArranged By – Paul RiserWritten-By – Lee Garrett, Syreeta WrightWritten-By, Producer – Stevie Wonder | 3:06 |
| 23 | –The Supremes | You Can't Hurry LoveWritten-By – Edward Holland, Jr.Written-By, Producer – Brian Holland, Lamont Dozier | 2:44 |
| 24 | –The Temptations | Papa Was A Rollin' StoneArranged By, Conductor – Paul RiserWritten-By – Barrett StrongWritten-By, Producer – Norman Whitfield | 6:57 |
| 25 | –Four Tops | Reach Out I'll Be ThereWritten-By – Edward Holland, Jr.Written-By, Producer – Brian Holland, Lamont Dozier | 2:59 |
| 26 | –Jimmy Ruffin | What Becomes Of The Broken HeartedProducer – William "Mickey" StevensonWritten-By – James Dean , Paul RiserWritten-By, Producer – William Weatherspoon | 2:58 |
| 27 | –Mary Wells | My GuyProducer – Smokey RobinsonWritten-By – William "Smokey" Robinson | 2:51 |
| 28 | –The Jackson 5 | I Want You BackWritten-By, Arranged By, Producer – The Corporation | 2:58 |
| 29 | –Undisputed Truth | Smiling Faces SometimesOrchestrated By – Jerry LongWritten-By – Barrett StrongWritten-By, Producer – Norman Whitfield | 3:15 |
| 30 | –Martha & The Vandellas | (Love Is Like A) HeatwaveWritten-By – Edward Holland, Jr.Written-By, Producer – Brian Holland, Lamont Dozier | 2:42 |
| 31 | –Gladys Knight & The Pips | Neither One Of Us (Wants To Be The First To Say Goodbye)Arranged By – Artie Butler, Michael OmartianProducer – Joe PorterWritten-By – Jim Weatherly | 4:20 |
| 32 | –Marvin Gaye & Tammi Terrell | Your Precious LoveProducer – Harvey Fuqua, Johnny BristolWritten-By – Nickolas Ashford, Valerie Simpson | 3:02 |
| 33 | –The Temptations | Ain't Too Proud To BegWritten-By – Edward Holland, Jr.Written-By, Producer – Norman Whitfield | 2:31 |
| 34 | –David Ruffin | My Whole World Ended (The Moment You Left Me)Producer – Johnny BristolWritten-By – James Roach, John Bristol, Pamela SawyerWritten-By, Producer – Harvey Fuqua | 3:31 |
| 35 | –The Miracles | Shop AroundWritten-By – William "Smokey" RobinsonWritten-By, Producer – Berry Gordy | 2:47 |
| 36 | –Martha & The Vandellas | Jimmy MackWritten-By – Edward Holland, Jr.Written-By, Producer – Brian Holland, Lamont Dozier | 2:52 |
| 37 | –Diana Ross & The Supremes | Someday We'll Be TogetherProducer – Johnny Bristol, Wade MarcusWritten-By – Harvey Fuqua, Jackey Beavers, John Bristol | 3:31 |
| 38 | –Marvin Gaye | What's Going OnArranged By – David Van DePitteWritten-By – Al Cleveland, Renaldo BensonWritten-By, Producer – Marvin Gaye | 3:51 |
| 39 | –Martha & The Vandellas | Dancing In The StreetWritten-By – Ivy Hunter, Marvin GayeWritten-By, Producer – William "Mickey" Stevenson | 2:37 |
| 40 | –The Supremes | Where Did Our Love GoWritten-By – Edward Holland, Jr.Written-By, Producer – Brian Holland, Lamont Dozier | 2:28 |
Photos courtesy of Motown Records Archives, except Supremes color photo courtesy of J. Randy Taraborrelli